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The synthesis, structure and properties of polypropylene nanocomposites

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dc.contributor.author Moodley, Vishnu Kribagaran
dc.date.accessioned 2007-11-12T09:59:31Z
dc.date.available 2007-11-12T09:59:31Z
dc.date.issued 2007
dc.identifier.other 308513
dc.identifier.uri http://hdl.handle.net/10321/143
dc.description Thesis (M.Tech.: Mechanical Engineering)-Dept. of Mechanical Engineering, Durban University of Technology, 2007 xiii, 101 leaves en
dc.description.abstract Polymer nanocomposites may be defined as structures that are formed by infusing layered-silicate clay into a thermosetting orthermoplastic polymer matrix. The nanocomposites are normally particle-filled polymers for which at least one dimension of the dispersed particles is in nanoscale. These clay-polymer nanocomposites have thus attracted great interest in industry and academia due to their exhibition of remarkable enhancements in material properties when compared to the virgin polymer or conventional micro and macro-composites. The present work describes the synthesis, mechanical properties and morphology of nano-phased polypropylene structures. The structures were manufactured by melt- blending low weight percentages of montmorillonite (MMT) nanoclays (0.5, 1, 2, 3, 5 wt. %) and polypropylene (PP) thermoplastic. Both virgin and infused polypropylene structures were then subjected to quasi-static tensile tests, flexural tests, micro-hardness tests, impact testing, compression testing, fracture toughness analysis, dynamic mechanical analysis, tribological testing. Scanning electron microscopy studies were then conducted to analyse the fracture surfaces of pristine PP and PP nanocomposite. X-ray diffraction studies were performed on closite 15A clay and polypropylene composites containing 0.5, 1, 2, 3 and 5 wt. % closite 15A nanoclay to confirm the formation of nanocomposites on the addition of organo clays. Transmission electron miscopy studies were then performed on the PP nanocomposites to determine the formation of intercalated, exfoliated or agglomerated nanoclay structures. Analysis of test data show that the mechanical properties increase with an increase in nanoclay loading up to a threshold of 2 wt. %, thereafter the material properties degrade. At low weight nanoclay loadings the enhancement of properties is attributed to the lower percolation points created by the high aspect ratio nanoclays. The increase in properties may also be attributed to the formation of intercalated and exfoliated nanocomposite structures formed at these loadings of clay. At higher weight loading, degradation in mechanical properties may be attributed to the formation of agglomerated clay tactoids. Results of XRD, transmission electron microscopy studies and scanning electron microscopy studies of the fractured surface of tensile specimens verify these hypotheses. en
dc.language.iso en en
dc.subject Materials en
dc.subject Composite materials en
dc.subject Polypropylene en
dc.subject Polymeric composites en
dc.subject Thermoplastics en
dc.subject Thermoplastic composites en
dc.subject Nanoparticles en
dc.subject Nanotechnology en
dc.subject Nanostructures en
dc.subject Mechanical engineering--Dissertations, Academic en
dc.title The synthesis, structure and properties of polypropylene nanocomposites en
dc.type Thesis en


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