Please use this identifier to cite or link to this item: https://hdl.handle.net/10321/1591
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dc.contributor.authorRedhi, Gan G.en_US
dc.contributor.authorEbenso, Eno E.en_US
dc.contributor.authorSingh, Surenen_US
dc.contributor.authorBahadur, Indraen_US
dc.contributor.authorRamjugernath, Dereshen_US
dc.date.accessioned2016-08-05T07:49:46Z-
dc.date.available2016-08-05T07:49:46Z-
dc.date.issued2015-
dc.identifier.citationSingh, S. et al. 2015. Influence of the alkyl group on thermophysical properties of carboxylic acids in 1-butyl-3-methylimidazolium thiocyanate ionic liquid at various temperatures. Journal of Chemical Thermodynamics. 89 : 104-111.en_US
dc.identifier.issn0021-9614-
dc.identifier.urihttp://hdl.handle.net/10321/1591-
dc.description.abstractIn the present study, influence of the alkyl group and temperature on the interactions between the carboxylic acid and ionic liquid (IL) mixtures were discussed in term of density and sound velocity measurements. The IL used in this study was 1-butyl-3-methylimidazolium thiocyanate ([BMIM]+[SCN]−). The density (ρ), and sound velocity (u), of the IL, acetic acid, propionic acid, and their corresponding binary systems {[BMIM]+[SCN]− (x1) + acetic or propionic acid (x2)} have been measured at T = (293.15, 298.15, 303.15, 308.15 and 313.15) K and at p = 0.1 MPa. The excess molar volumes, View the MathML sourceVmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and sound velocity data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions that exist between the IL and carboxylic acid mixtures.en_US
dc.format.extent8 pen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Chemical Thermodynamicsen_US
dc.subjectDensityen_US
dc.subjectSound Velocityen_US
dc.subjectIonic Liquiden_US
dc.subjectCarboxylic aciden_US
dc.subjectRedlich-Kister polynomial equationen_US
dc.titleInfluence of the alkyl group on thermophysical properties of carboxylic acids in 1-butyl-3-methylimidazolium thiocyanate ionic liquid at various temperaturesen_US
dc.typeArticleen_US
dc.publisher.urihttp://www.sciencedirect.com/science/article/pii/S0021961415001366en_US
dc.dut-rims.pubnumDUT-005116en_US
dc.description.availabilityCopyright: 2015. Elsevier. Due to copyright restrictions, only the abstract is available. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Journal of Chemical Thermodynamics, 2015. Vol 89 : 104-111.en_US
dc.identifier.doihttps://doi.org/10.1016/j.jct.2015.05.004-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.fulltextNo Fulltext-
Appears in Collections:Research Publications (Applied Sciences)
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