Please use this identifier to cite or link to this item: http://hdl.handle.net/10321/1043
Title: Densities and excess molar volume for the ternary systems (1-Butyl-3-methylimidazolium methyl sulphate + Nitromethane + Methanol or Ethanol or 1-Propanol) at T = (303.15 and 313.15) K
Authors: Bahadur, Indra 
Deenadayalu, Nirmala 
Keywords: Density;Excess molar volume;Ionic liquid;Alcohol;Nitromethane
Issue Date: 2013
Publisher: SA Epublications
Source: Bahadur, I. and Deenadayalu, N. 2013. Densities and Excess Molar Volume for the Ternary Systems (1-Butyl-3-methylimidazolium methyl sulphate + Nitromethane + Methanol or Ethanol or 1-Propanol) at T = (303.15 and 313.15) K. S. Afr. J. Chem. 66: 200-206.
Abstract: The densities of the ternary systems containing the ionic liquid 1-butyl-3-methylimidazolium methyl sulphate ([BMIM]+[MeSO4]–) were determined. The ternary systems studied were ([BMIM]+[MeSO4]– + nitromethane + methanol or ethanol or 1-propanol) at the temperatures (303.15 and 313.15) K. The ternary excess molar volumes were calculated from the experimental densities at each temperature, being negative for all mole fractions of the ionic liquid. The minimum ternary excess molar volumes increase with an increase in temperature for the systems ([BMIM]+[MeSO4]– + nitromethane + methanol or ethanol), and decrease for the system ([BMIM]+ [MeSO4]–+ nitromethane + 1-propanol). The results are interpreted in terms of the alcohol chain length and the intermolecular interactions.
URI: http://hdl.handle.net/10321/1043
Appears in Collections:Research Publications (Applied Sciences)

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