The effect of heavy metal composition on the performance of sugarcane bagasse as an adsorbant in water treatment

Abstract

Wastewater produced by the industries is potentially harmful to the ecosystem because of various contaminants like heavy metals that find their way into soil and water supplies. Industrial waste constitutes different kinds of metal which contaminate natural water. Heavy metals can build up in the environment and enter living organisms through chain elements such as the food chain and therefore, pose a major health risk to living organisms. The situation has been worsened by the absence of broadly accepted heavy metal treatment techniques, thus this challenge continues to receive considerable attention from stakeholders including scientists and researchers. While many technologies have been proposed such as reverse osmosis, flocculation, ion exchange and so on and so forth, they continue to suffer from a number of drawbacks including generation of secondary wastes and cost ineffectiveness. Thus, in the present study, adsorption was chosen as a cost effective, efficient, and environmentally friendly treatment process. Sugar cane milling production produces a lot of sugar cane bagasse which is considered as environmental waste if not disposed properly. It is imperative to remove heavy metals from polluted water before discharging it into the environment, rivers and lakes using sustainable techniques. Heavy metal removal from wastewater using low-cost adsorbents like sugarcane bagasse addresses two problems: removal of pollutants from water and utilization of agricultural waste. This study evaluated the performance of sugarcane bagasse in the removal of heavy metals. Sugarcane bagasse was characterized to determine the functional groups, the porosity and surface area, crystallinity and morphology using FTIR, SEM and XRD. One factor at a time (OFAT) approach was used to evaluate the effect of operating parameters on the removal of heavy metal ions. A 3-system component of the stock solution of synthesized wastewater namely single, binary and ternary were studied. The 3 metal ions evaluated were Copper, Chromium and Cadmium. The factors considered in the OFAT design of experiments were contact time (30-240 mins), adsorbent dosage (5-30g/L), initial concentration (50-500 mg/L), pH(2-9), and particle size (75-600 μm). It was observed that all adsorption parameters had an effect on the adsorption rate. However, an adsorption dosage had a greater impact on the adsorption rate. An increase in the adsorption dosage from (5-20 g) showed that the percentage removal efficiency for chromium, copper and cadmium increased from (40-72%, 44-75% and 39-59%) in a single metal system. In addition, the percentage removal increased from (34-62% for chromium, 47- 78% for copper, and 34-62% for cadmium) in a binary metal system. Furthermore, the percentage removal increased from (38-52%, 40-59% and 24-43%) for chromium, copper, and cadmium in a ternary metal system. Adsorption capacity of the adsorbent was determined using the optimal operating parameters obtained from the OFAT design of experiments. Langmuir and Freundlich isotherms were used to analyze the adsorption data. The OFAT design of experiments resulted in producing the optimum conditions for adsorption. The optimum conditions for maximum adsorption were, contact time (180 mins), initial concentration (50 mg/L), pH (7), dosage (20 g), particle size (340-450 μm) and a mixing speed of 150 rpm. Adsorption capacities differed between the 3 system components. Maximum adsorption capacities of 38.41 mg/L were registered for copper ions and was recorded for the single component system. Stock solutions containing copper ions registered the highest adsorption capacity. There was a significant decrease in the maximum adsorption capacities for copper ions of the binary and ternary system components which were 21.45 mg/L and 1.237 mg/L respectively. This was attributed to the co-metal ion dependence in both the binary and ternary system components. In conclusion, the study showed that sugarcane bagasse can be used as an adsorbent in the efficient removal of heavy metal ions present in wastewater.