Please use this identifier to cite or link to this item: https://hdl.handle.net/10321/5320
Title: A review of the implications of polyethylene plastics when utilized as chemical storage tanks
Authors: Khanyi, Nhlanhla F. 
Tabakov, Pavel Y. 
Inambao, Freddie L. 
Keywords: Chemical;Degradation;Environmental stress cracking;High-density polyethylene;Storage tank
Issue Date: 1-May-2024
Publisher: Journal of Aeronautical Materials
Source: Khanyi, N.F., Tabakov, P.Y. and Inambao, F.L. 2024. A review of the implications of polyethylene plastics when utilized as chemical storage tanks. Journal of Aeronautical Materials. 44(01): 178-202 (25).
Journal: Journal of Aeronautical Materials; Vol. 44, Issue 01 
Abstract: 
Many studies have been conducted to investigate the impact or influence of polyethylene (PE)
plastic when used as chemical liquid storage. Herein, this literature addresses the factors that
contribute to the degradation of chemical storage tanks as a result of PE plastics and how they
can be mitigated. This is achieved by reviewing and discussing the significant properties of
High-density polyethylene (HDPE), which have been reported to degrade the chemicals stored
in these storage tanks. The method of cross-linking the PE was reviewed with its preceding
processes that involve chemical and physical processes. The influence of each agent on the
resulting properties is discussed in detail including the effect of cross-linking degree. These
methods were found to be significant in improving some of the properties of HDPE to better
store chemical substances. Nonetheless, it was established that the main concern of PE plastics
is environmental stress cracking (ESC), which causes unexpected cracks within the HDPE
storage tanks, thus degrading the substance contained. The currently used method or test (bentstrip)
to determine the resistance of PE to ESC and techniques used to monitor it were reviewed
and discussed in detail. Consequently, the literature suggests that the relationship between the
density of PE and its ESC susceptibility has been found to be significant. However, research
has shown that relying solely on density as a predictor of ESC in PE when exposed to chemical
substances is insufficient, and further studies should be conducted to investigate other
parameters that contribute to ESC in PE. In addition, the review suggests that future research
should focus on studying ESC resistance of newly developed Nano-filled PE composites or
biodegradable PE variants, as these are future materials for storing chemical substances
conveniently.
URI: https://hdl.handle.net/10321/5320
ISSN: 1005-5053
Appears in Collections:Research Publications (Engineering and Built Environment)

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