Please use this identifier to cite or link to this item: https://hdl.handle.net/10321/850
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dc.contributor.authorDeenadayalu, Nirmalaen_US
dc.contributor.authorLetcher, Trevor M.en_US
dc.date.accessioned2013-04-08T07:40:27Z
dc.date.available2013-04-08T07:40:27Z
dc.date.issued2005-06-01-
dc.identifier.citationDeenadayalu, Nirmala and Letcher, T. M. Application of the extended real associated solution theory to excess molar enthalpies and excess molar volumes of binary mixtures of (benzene or 1-alkanol + quinoline).' 'Journal of Molecular Liquids. 121,2-3 (2005): 143-147en_US
dc.identifier.urihttp://hdl.handle.net/10321/850-
dc.description.abstractExcess molar enthalpies and excess molar volumes of binary mixtures of (benzene or methanol or ethanol or 1-propanol or 1- butanol+quinoline) as a function of composition at a pressure of 1 atm and a temperature of 298.15 K have been used to test the Extended Real Solution Theory, ERAS, of nonelectrolyte solutions. The ERAS theory accounts for free volume effects according to the Flory–Patterson theory and for association effects: self and crossassociation between the molecules involved. The ERAS theory results for the binary mixtures (benzene or an alkanol+quinoline) indicates strong hydrogen bonding effects between unlike molecules given by the predicted hydrogen bonding energy between two dissimilar compounds. Comparison is also made between the chemical and physical contribution to the ERAS theory. The Extended Real Associated Solution theory describes the published Vm E data better than the published Hm E data.en_US
dc.format.extentpp. 143-147 (5 p.)en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.rightsThe electronic version of the article published in Journal of Molecular Liquids 2005, 121(2-3): 143-147 © 2005 copyright Elsevier. Journal of Molecular Liquids is available online at: http://www.sciencedirect.com/science/article/pii/S0167732205000310en_US
dc.subjectExcess molar enthalpyen_US
dc.subjectExcess molar volumeen_US
dc.subjectAlkanolsen_US
dc.subjectERASen_US
dc.subject.lcshMolecular volumeen_US
dc.subject.lcshChemistry, Physical and theoreticalen_US
dc.titleApplication of the extended real associated solution theory to excess molar enthalpies and excess molar volumes of binary mixtures of (benzene or 1-alkanol + quinoline)en_US
dc.typeArticleen_US
dc.publisher.urihttp://dx.doi.org/10.1016/j.molliq.2004.12.002en_US
dc.identifier.doi10.1016/j.molliq.2004.12.002-
item.grantfulltextnone-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.languageiso639-1en-
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
Appears in Collections:Research Publications (Applied Sciences)
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