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|Title:||Pathways of 3-biofules (hydrogen, ethanol and methane) production from petrochemical industry wastewater via anaerobic packed bed bafﬂed reactor inoculated with mixed culture bacteria||Authors:||Elreedy, Ahmed
Enitan, Abimbola Motunrayo
Kumari, Sheena K.
|Keywords:||Mono-ethylene glycol;Bio-hydrogen;Ethanol and methane;Anaerobic packed bed bafﬂed reactor;Compartment-wise proﬁles;Kinetic studies;Microbial analysis||Issue Date:||2016||Publisher:||Elsevier||Source:||Elreedy, A. et al. 2016. Pathways of 3-biofules (hydrogen, ethanol and methane) production from petrochemical industry wastewater via anaerobic packed bed bafﬂed reactor inoculated with mixed culture bacteria. Energy Conversion and Management. 122: 119-130.||Journal:||Energy conversion and management (Online) ItemCrisRefDisplayStrategy.journals.deleted.icon||Abstract:||Simultaneous production of 3-biofuels (hydrogen, ethanol and methane) as by-products of the biodegra-dation of petrochemical wastewater containing MEG via anaerobic packed bed bafﬂed reactor (AnPBBR), was extensively investigated. A four-chambered reactor supported by polyurethane sheets, was operated at a constant hydraulic retention time (HRT) of 36 h and different organic loading rates (OLRs) of 0.67, 1, 2 and 4 gCOD/L/d. The maximum speciﬁc H2 and CH4 production rates of 438.07 ± 43.02 and 237.80 ± 21.67 ml/L/d were respectively achieved at OLR of 4 gCOD/L/d. The residual bio-ethanol signif-icantly increased from 57.15 ± 2.31 to 240.19 ± 34.69 mg/L at increasing the OLR from 0.67 to 4 gCOD/L/d, respectively. The maximum MEG biodegradability of 98% was attained at the lowest OLR. Compartment-wise proﬁles revealed that the maximum H2 and ethanol production were achieved at HRT of 9 h (1st compartment), while the CH4 production was peaked at HRTs of 27 and 36 h (last two compartments). Kinetic studies using Stover–Kincannon and completely stirred tank reactor (CSTR) in series models were successfully applied to the AnPBBR overall and compartment-to-compartment performance, respectively. The economic evaluation strongly revealed the potentials of using AnPBBR for simultaneous treatment and bio-energy production from petrochemical wastewater as compared to the classical anaerobic bafﬂed reactor (ABR). Microbial analysis using Illumina MiSeq sequencing showed a diversity of bacterial com-munity in AnPBBR. Proteobacteria (36.62%), Firmicutes (20.85%) and Bacteroidetes (3.44%) were the most dominant phyla.||URI:||http://hdl.handle.net/10321/2375||ISSN:||0196-8904 (print)
|Appears in Collections:||Research Publications (Water and Wastewater Technology)|
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